Second-harmonic generation in centrosymmetric crystals of chiral molecules
نویسندگان
چکیده
منابع مشابه
Second harmonic generation from the ‘centrosymmetric’ crystals
Second harmonic generation (SHG) is a well known non-linear optical phenomena which can be observed only in non-centrosymmetric crystals due to non-zero hyperpolarizability. In the current work we observed SHG from a Zn(II) complex which was originally thought to have crystallized in the centrosymmetric space group C2/c. This has been attributed to the unequal antiparallel packing of the metal ...
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A simple model is presented for interpreting the presence of substantial second harmonic generation (SHG) activity from assemblies of centrosymmetric molecular building blocks. Using butadiene as a computationally tractable centrosymmetric model system, time-dependent Hartree-Fock calculations of the nonlinear polarizability of butadiene dimer were well-described through exciton coupling argume...
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On the basis of the Ewald-Kornfeld formulation, we study the effective susceptibility of second-harmonic generation (SHG) in colloidal crystals, which are made of graded metallodielectric nanoparticles with an intrinsic SHG susceptibility suspended in a host liquid. We find a large enhancement and redshift of SHG responses, which arises from the periodic structure, local field effects, and grad...
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ژورنال
عنوان ژورنال: Physical Review Letters
سال: 1990
ISSN: 0031-9007
DOI: 10.1103/physrevlett.65.37